PFAS in Drinking Water: Treatment Technologies and Remediation Strategies


The Dangers of PFAS in Drinking Water

PFAS in drinking water has become an increasingly concerning issue in recent years, as these man-made chemicals have been found in water supplies across the United States and other parts of the world. Many states are finding that PFAs contamination is more widespread than originally thought, and they are only now beginning to address this problem.

PFAS in drinking water is a growing concern for many people, as exposure to these chemicals has been linked to potential health risks. The federal government, through the EPA, has set health advisory levels for some PFAS in drinking water, while some states have established their own, more stringent, standards.

In this article, we will explore the basics of PFAS in drinking water, their potential health effects, and what you can do to protect yourself from exposure.

What Are PFAS?

PFAS (per- and polyfluoroalkyl substances) are a group of more than 4,700 man-made chemicals that have been used in a wide range of products since the 1940s. Due to their chemical stability, PFAS do not break down easily in the environment, leading to widespread contamination in water, soil, and air.

PFAS are highly resistant to heat, water, and oil, which makes them useful in products such as non-stick cookware, waterproof clothing, and food packaging. They are also used in firefighting foam, which led to their widespread use. As a result, we are finding PFAS in groundwater and drinking water sources across the country.

How do PFAS get into my drinking water?

PFAS can get into drinking water through several ways, including:

  1. Discharge from industrial facilities: PFAS are used in many industrial processes, and facilities that manufacture or use these chemicals can release them into the environment.
  2. Landfills: Landfills that contain products or materials that contain PFAS can leach these chemicals into nearby groundwater.
  3. Wastewater treatment plants: PFAS can be present in wastewater, and treatment plants that do not remove these chemicals can release them into the environment.
  4. Firefighting foam: Firefighting foam that contains PFAS can be used during emergencies, and the foam can contaminate nearby soil and groundwater.
  5. Contaminated soil: PFAS can leach from contaminated soil into groundwater, which can then contaminate drinking water sources.

Once PFAS are in the environment, they can persist for a long time and can accumulate in the bodies of humans and animals. This is why they are known as forever chemicals.

What are the health effects of PFAS exposure?

Health Effects of PFAS ExposureExposure to PFAS has been linked to a range of potential health effects, including:

  • Increased cholesterol levels
  • Changes in liver function
  • Decreased vaccine response in children
  • Increased risk of kidney and testicular cancer
  • Developmental effects in fetuses and infants

While the full extent of the health effects of PFAS is still being studied, some experts believe that even low levels of exposure may be harmful.

How can I protect myself from PFAS exposure?

There are several steps you can take to reduce your exposure to PFAS. These include using alternative products that do not contain PFAS, such as stainless steel cookware and glass food containers, and avoiding products with stain and water-resistant coatings. You can also install a water filtration system that is specifically designed to remove PFAS from your drinking water.

Current Regulations and Guidelines

Federal Regulations

On March 14, 2023, EPA announced the proposed National Primary Drinking Water Regulation (NPDWR) for six PFAS including:

  1. perfluorooctanoic acid (PFOA)
  2. perfluorooctane sulfonic acid (PFOS)
  3. perfluorononanoic acid (PFNA)
  4. hexafluoropropylene oxide dimer acid (HFPO-DA commonly known as GenX Chemicals)
  5. perfluorohexane sulfonic acid (PFHxS)
  6. perfluorobutane sulfonic acid (PFBS)

The proposed PFAS NPDWR does not require any actions until it is finalized. EPA anticipates finalizing the regulation by the end of 2023. EPA expects that if fully implemented, the rule will prevent thousands of deaths and reduce tens of thousands of serious PFAS-attributable illnesses.

EPA is proposing a National Primary Drinking Water Regulation (NPDWR) to establish legally enforceable levels, called Maximum Contaminant Levels (MCLs), for the above mentioned PFAS compounds.

The following table summarizes the proposed federal drinking water standards for PFAS.

Compound Proposed MCLG Proposed MCL (enforceable levels)
PFOA Zero 4.0 parts per trillion (also expressed as ng/L)
PFOS Zero 4.0 ppt
PFNA 1.0 (unitless)

Hazard Index

1.0 (unitless)

Hazard Index

PFHxS
PFBS
HFPO-DA (commonly referred to as GenX Chemicals)

The proposed rule would also require public water systems to:

  • Monitor for these PFAS
  • Notify the public of the levels of these PFAS
  • Reduce the levels of these PFAS in drinking water if they exceed the proposed standards.

State Regulations

Several states, including Rhode Island and Washington, have proposed Drinking Water regulations for PFAS, reinforcing the fact that this is an area of regulation that is developing quickly. The following chart lists the current PFAS standards for states with established limits.

Participating States Concentration Level Type of Regulation
Alaska, Colorado, Delaware, Maine, New Mexico, and Ohio 70 ppt Follow the EPA Standard:  PFOS and PFOA combined (Notification)
California 5.1 ppt PFOA (Notification)
6.5 ppt PFOS (Notification)
Connecticut 70 ppt 5 PFAS substances combined:  PFHpA, PFHxS, PFNA, PFOS, and PFOA (Notification)
Massachusetts 20 ppt (Stated in the regulation as 20 ng/L) 6 PFAS Substances combined — PFOA, PFOS, PFHxS, PFNA, PFHpA, and PFDA (MCL)
Michigan 6 ppt PFNA (MCL)
8 ppt PFOA (MCL)
16 ppt PFOS (MCL)
51 ppt PFHxS (MCL)
370 ppt HFPO-DA (MCL)
420 ppt PFBS (MCL)
140,000 ppt PFHxA (MCL)
Minnesota 15 ppt PFOS (Guidance)
35 ppt PFOA (Guidance)
47 ppt PFHxS (Guidance)
2,000 ppt PFBS (Guidance)
7,000 ppt PFBA (Guidance)
New Hampshire 11 ppt PFNA (MCL)
12 ppt PFOA (MCL)
15 ppt PFOS (MCL)
18 ppt PFHxS (MCL)
New Jersey 13 ppt PFNA and PFOS (MCL)
14 ppt PFOA (MCL)
New York 10 ppt PFOA and PFAS (MCL)
North Carolina 140 ppt GenX (Guidance)
Ohio 21 ppt PFNA (Guidance)
140 ppt PFHxS (Guidance)
700 ppt Gen X (Guidance)
140,000 ppt PBFS (Guidance)
Vermont 20 ppt (Stated in the regulation as 0.000020 mg/L) 5 PFAS substances combined:  PFHpA, PFHxS, PFNA, PFOS and PFOA (MCL)

 

Methods for Removing PFAS from Drinking Water

Various treatment methods are available for removing PFAS from drinking water. In this section, we will explore four of the most common techniques:

Activated Carbon Filtration

Activated carbon filters are a very effective treatment method for removing PFAS from drinking water. Key features and attributes of this technology are:

  • Uses porous carbon material to adsorb PFAS from water
  • Effective for removing a wide range of PFAS compounds
  • Can be used in both municipal and household filtration systems

Ion Exchange Resins

Ion exchange resins have recently been developed that are extremely effective at removing PFAS from water. These resins have the following attributes:

  • Utilizes specially designed resins to bind PFAS molecules
  • Highly effective for removing short-chain PFAS
  • Requires periodic regeneration or replacement of the resin

Reverse Osmosis

Reverse osmosis (RO) filtration can effectively remove PFAS from drinking water. This technology is well understood and is widely used for treating drinking water.

RO technology offers the following benefits:

  1. Forces water through a semi-permeable membrane, leaving PFAS behind
  2. Effective for removing both long- and short-chain PFAS
  3. Requires a high-pressure pump and may produce a significant amount of wastewater

Nanofiltration

  • Similar to reverse osmosis but uses a more selective membrane
  • Can effectively remove a wide range of PFAS compounds
  • Less energy-intensive compared to reverse osmosis
Treatment Method Key Features Applications
Activated Carbon – Porous carbon material<br>- Wide range of PFAS removal Municipal, Household
Ion Exchange Resins – Special resins<br>- Effective for short-chain PFAS Municipal, Household
Reverse Osmosis – Semi-permeable membrane<br>- High-pressure pump Municipal, Household
Nanofiltration – Selective membrane<br>- Less energy-intensive Municipal, Household

 

Testing Your Drinking Water for PFAS Contamination

If you are concerned about PFAS in your drinking water, you can have it tested for contamination.

There are several analytical methods available to detect and quantify PFAS in drinking water, such as liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). You can also use home test kits to evaluate your home’s drinking water.

Regular testing of drinking water sources is essential to ensure that PFAS concentrations remain below the recommended guidelines.

Final Take

PFAS in drinking water is a growing concern, and it’s important to be informed about the potential risks and take steps to protect yourself from exposure. By understanding the basics of PFAS and taking proactive measures, you can help ensure that you and your family are drinking safe and healthy water.

Jordan

I'm an environmental scientist with a degree in Environmental Science and over 15 years of experience tackling environmental challenges, particularly PFAS contamination. My journey in this field is driven by a deep commitment to public education and environmental health advocacy. I strive to break down complex environmental issues into understandable concepts, making them accessible and actionable for everyone. As an author, my goal is to not only inform but also inspire our community to take meaningful steps towards environmental responsibility.

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